Hi,
Sorry I haven't got a copy of the standard infront of me (it is Sunday) so please bear with me.
The accuracy and precision of
methods can be assessed using protocols in ISO 5725. This involves analysis of several samples by multiple laboratories and using stats to get the figures. CCFRA publish a document specifically for micro methods.
BRC require that we assess the ongoing accuracy of the site
laboratory.
Issue 5 requires we operate to the principles of ISO14025. This standard says that a laboratory should test the accuracy of testing by participation in an accredited scheme
where such a scheme exists. I would class such schemes as
'ring testing' ie several labs testing an unknown sample and reporting results back to an independent organisation that collates and statistically analyses the results. Some schemes use 'expert' labs to provided the 'real result'.
Such schemes can now be certified by UKAS or country equivalents. I'm not sure of the standard (may be PD 6644-1:1999, ISO/IEC Guide 43-1:1997 Proficiency testing by interlaboratory comparisons).
Check out the LGC (
http://www.lgcpt.com/schemes.aspx) or Bipea (
http://www.bipea.org/).
Obviously if a scheme does not exist, the scheme you described - where a central function performs the 'ring testing' is acceptable (providing auditable and defendable).
Where ring testing is not available you must assess performance by other means. This I would class as
'proficiency testing' in a general sense. It is best practice to do this to back up the ring testing. I would include:
Analysis of internal quality assurance samples eg unknown reference samples or 'spiked' samples (ideally anaysed by an 'expert' certified lab).
Analysis of a sample followed by analysis of an expert laboratory
Analysis of known certified materials
To demonstrate compliance to an auditor I would place in order:
Use of a certified proficiency scheme (ring testing)
Use of an independent non certified scheme (ring testing)
Use of a central function scheme (ring testing)
Supported by other means of proficiency testing:
Analysis of internal quality assurance samples
Analysis of a sample followed by analysis of an expert laboratory
Analysis of known certified materials
Micro schemes are always fun - depends to a great extent on how representative the sample is.
I'm afraid that whatever my views, it always comes down to the auditor on the day as to what he thinks is acceptable.
All I can say is that it got me through my Issue 5 audit!!
To sum up I'd say ring tests are one of the options available as part of proficiency testing.
Hope it helps
Rob