In my old spice plant, we noticed things like red bell pepper (powder and flake) would often clump. Boss said it was due to the natural sugar content from the peppers (we didn't own the product in this plant, so I'm unable to speculate what the material spec would have said). SiO2 was commonly added to products we would blend with red bell because of this, but it still didn't totally solve the problem. We also observed that warmer summer temps in our warehouse caused more bricking, practically melting these low moisture powders and flakes together: green bell not so much for some reason, but chopped carrots and flakes would also do it to an extent.
When you mention blending doesn't add heat, can I ask what type of blending you're talking about? We used tumbling blenders and a ribbon blender, and I can say the ribbon blender did indeed warm the product. Not in a way that affected safety, but absolutely the ribbon blender's mechanical agitation and friction would warm the product. But because the blender used those blades, it was a preferred method for items using red bell to break up the clumps. And sometimes we would run the bricked red bell through that machine before using elsewhere in our process just to break up the chunks.